By Patrick Modiano
Il faut croire que parfois notre mémoire connaît un processus analogue à celui des photographs Polaroïd. Pendant près de trente ans, je n’ai guère pensé à Jansen. Nos rencontres avaient european lieu dans un laps de temps très court docket. Il a quitté l. a. France au mois de juin 1964, et j’ai écris ces lignes en avril 1992. Je n’ai jamais ecu de nouvelles de lui et j’ignore s’il est mort et vivant. Son memento était resté en hibernation et voilà qu’il resurgit au début de ce printemps 1992. Est-ce parce que j’ai retrouvé los angeles picture de mon amie et moi, au dos de laquelle un tampon aux lettres bleues indique : picture Jansen. copy interdite ? Ou bien pour los angeles easy raison que les printemps se ressemblent ?
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Additional info for Chien de printemps
4. As the SIMS spectra c o n f m that Rh-CI contact exists, whereas RhCl, and RhCl, species, for which SIMS is particularly sensitive through the RhCl; signal, do not appear to be present, it is believed that the majority of the Cl-containing Rh complexes on the fresh catalyst contains one C1 atom only and is of the form [RhCl(OH)3(H20)2]-. Note that this conclusion could not have been drawn on the basis of XPS alone, because alumina is known to strongly bind C1- ions. The SIMS spectra are of great value here because they confirm that at least a part of the C1- is coordinated to rhodium.
Regions. On the other hand, the intensity rise of Na' in matrix regions indicates that migration of some zeolite debris migration into the catalyst matrix may occur. The previous examples show that imaging SIMS data can be valuable in catalyst deactivation studies, as trace amounts of deposited contaminantsand their positions relative to the active phase of the catalyst can be determined. However, nowadays the resolution of ultimately 50 nm restricts the application to a limited number of systems, as many catalysts contain particles of much smaller size.
50*5'used the 4-nm thick native oxide overlayer of an aluminum foil as a model support. The A1 2p and 0 1s binding energies of this aluminum oxide film are consistent with values obtained for y-alumina, and SIMS spectra indicate the presence of hydroxyl groups. Rhodium catalysts were prepared by the wet-chemical exchange method described above. Figure 10 (bottom) shows positive and negative static SIMS spectra of a freshly prepared Rh/A1203/AI catalyst. These spectra should be compared with the RhCl, precursor spectra given in Figure 10 (top).