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Lipids 6, 531-6. 871-874. De la Roche, I. , Weber, E. J. and Alexander, D. E. (1971c) Lipids 6, 531-6. Farre-Rovira, R. (1975). Circ. Farm. 33, 399-417. Farre-Rovira, R. and Costes, C. (1974). Physiol. Veg. 12, 251-288. Farrington, W. Η. H. and Shearer, G. (1981). J. Sci. Food Agric 32, 948-950. 2 ACYL LIPIDS IN CEREALS 31 Fishwick, M. J. and Wright, A. J. (1980). Phytochemistry 19, 55-59. Fujino, Y. (1978). Cereal Chem. 55, 559-571. Fujino, Y. and Miyazawa, T. (1979). Biochim. Biophys. Acta 572, 442-451.

J. and Laidman, D. L. (1975). Phytochemistry 14, 2639-2645. Cuming, A. C. and Osborne, D. J. (1978). Planta 139, 219-226. Dartary, R. D. and Pomeranz Y. (1965). J. Food Sci. 30, 577-582. Dalton, J. L. and Mitchell, H. L. (1959). J. Agric. Food Chem. 7, 570-573. De la Roche, I. , Alexander, D. E. and Weber, E. J. (1971a). Crop Sci. 11, 856-859. De la Roche, I. , Weber, E. J. and Alexander, D. E. (1971c). Lipids 6, 531-6. 871-874. De la Roche, I. , Weber, E. J. and Alexander, D. E. (1971c) Lipids 6, 531-6.

Fig. 3 shows the possible pathway by which these transformations may occur and illustrates the interrelationships of the sterols (Goodwin, 1980). Side-chain modification proceeds through the 24-methylene to the 24-methyl sterols or by a second methylation produc­ ing the 24-ethylidene group and then the 24-ethyl sterols. Nuclear trans­ formations include the opening of the cyclopropane ring, demethylations at 8 7 5 C-4 and C-14 and the Δ —»Δ —»Δ steps. It can be seen that the range of sterols found in cereal grains represents not only a variety of end-products but also a set of intermediates common to the sterol biosynthetic pathway in plants.

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