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Without further information the configuration of the 11-epoxide would be unknown. However, previous analysis of the trans-epoxide configuration would designate it as an 1 IR-epoxide. A chiral method to analyse the third type of epoxyalcohol, the one with the alcohol vicinal to the olefin and with a /3, ')'epoxide, was developed by Hamberg [122). These isomers derived from HPODE are 12,13-epoxy-ll-hydroxy-9octadecenoic and 9,10-epoxy-ll-hydroxy-12-octadecenoic acids. In this method the epoxyalcohol is first analysed by spectral methods (as above) to determine if the epoxide is cis or trans.

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